100 points per title, TT and RR. So far, 3000 points have been awarded to listed riders (for non-VDS champs see the appropriate Nat Champ threads):

National RR Champs:

Belarus: Yauheni Hutarovich    100
Belgium: Tom Boonen    100
Denmark: Matti Breschel    100
Estonia: Rein Taaramae    100
France: Dmitri Champion    100
Germany: Martin Reimer    100
Ireland: Nicolas Roche    100
Italy: Filippo Pozzato    100
Luxembourg: Andy Schleck    100
Kazakhstan: Dmitriy Fofonov    100
Norway: Kurt-Asle Arvesen    100
Russia: Serguei Ivanov    100
Spain: Ruben Plaza Molina    100
Switzerland: Fabian Cancellara     100

National TT Champs:

Canada: Svein Tuft    100
Czech Republic: Frantisek Rabon    100
Denmark: Lars Bak    100
Estonia: Rein Taaramae    100
Germany: Bert Grabsch    100
Italy: Marco Pinotti    100
Kazakhstan: Andrey Mizourov    100
Lithuania: Ignas Konovalovas    100
Luxembourg: Kim Kirchen    100
Norway: Edvald Boasson Hagen    100
Poland: Maciej Bodnar    100
Portugal: Tiago Jose Pinto Machado 100
Slovenia: Janez Brajkovic    100
Spain: Alberto Contador    100
Switzerland: Rubens Bertogliati    100
Ukraine: Andriy Grivko    100

Will update as results become known--latest updates will be bolded.